In situ decoration of laser-scribed graphene with TiO2 nanoparticles for scalable high-performance micro-supercapacitors

نویسندگان

چکیده

Graphene-based miniaturized supercapacitors, obtained via laser conversion of suitable precursors, have been attracting recent attention for the production energy storage small-scale devices. In this work, a one-pot synthesis TiO2 nanoparticles embedded in porous graphene-based electrodes has with LightScribe® technology, by converting precursor materials through absorption DVD burner infrared light. Enhanced electrochemical performance devices achieved thanks to combination faradic surface reactions, arising from metal oxide nanoparticles, conventional double layer capacitance, graphene. Micro-supercapacitors, consisting TiO2-graphene electrodes, tested investigating two hydrogel polymer electrolytes, based on polyvinyl alcohol/H3PO4 and alcohol/H2SO4, respectively. Specific areal capacitance up 9.9 mF/cm2 are devices, corresponding volumetric 13 F/cm3 doubling pristine device results. The micro-supercapacitors specific power 0.22 μWh/cm2 39 μW/cm2, along cyclability greater than 3000 cycles. These high-performance results suggest laser-scribed nanostructures as remarkable candidates environment-friendly, large-scale low-cost applications.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

In situ decoration of graphene sheets with gold nanoparticles synthetized by pulsed laser ablation in liquids

The demand for nanocomposites of graphene and carbonaceous materials decorated with metallic nanoparticles is increasing on account of their applications in science and technology. Traditionally, the production of graphene-metal assemblies is achieved by the non-environmentally friendly reduction of metallic salts in carbonaceous suspensions. However, precursor residues during nanoparticle grow...

متن کامل

Cost Effective and Scalable Synthesis of MnO2 Doped Graphene in a Carbon Fiber/PVA: Superior Nanocomposite for High Performance Flexible Supercapacitors

In the current study, we report new flexible, free standing and high performance electrodes for electrochemical supercapacitors developed througha scalable but simple and efficient approach. Highly porous structures based on carbon fiber and poly (vinyl alcohol) (PVA) were used as a pattern. The electrochemical performances of Carbon fiber/GO-MnO2/CNT supercapacitors were characteriz...

متن کامل

Fabrication of Graphene/MoS2 Nanocomposite for Flexible Energy Storage

In the present work,MoS2 decorated graphene nanocomposite powders were synthesized by laser scribing method.Theobtainedflexible light-scribed graphene/MoS2composites are very suitableas micro-supercapacitors and thus their performance was evaluated at different concentrations.The effect of laser scribing process to reducegraphene oxide (GO) was investigated. The GO/MoS2composite wassynthesized ...

متن کامل

Mass production of highly-porous graphene for high-performance supercapacitors

This study reports on a facile and economical method for the scalable synthesis of few-layered graphene sheets by the microwave-assisted functionalization. Herein, single-layered and few-layered graphene sheets were produced by dispersion and exfoliation of functionalized graphite in ethylene glycol. Thermal treatment was used to prepare pure graphene without functional groups, and the pure gra...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Carbon

سال: 2021

ISSN: ['0008-6223', '1873-3891']

DOI: https://doi.org/10.1016/j.carbon.2021.01.129