In situ decoration of laser-scribed graphene with TiO2 nanoparticles for scalable high-performance micro-supercapacitors
نویسندگان
چکیده
Graphene-based miniaturized supercapacitors, obtained via laser conversion of suitable precursors, have been attracting recent attention for the production energy storage small-scale devices. In this work, a one-pot synthesis TiO2 nanoparticles embedded in porous graphene-based electrodes has with LightScribe® technology, by converting precursor materials through absorption DVD burner infrared light. Enhanced electrochemical performance devices achieved thanks to combination faradic surface reactions, arising from metal oxide nanoparticles, conventional double layer capacitance, graphene. Micro-supercapacitors, consisting TiO2-graphene electrodes, tested investigating two hydrogel polymer electrolytes, based on polyvinyl alcohol/H3PO4 and alcohol/H2SO4, respectively. Specific areal capacitance up 9.9 mF/cm2 are devices, corresponding volumetric 13 F/cm3 doubling pristine device results. The micro-supercapacitors specific power 0.22 μWh/cm2 39 μW/cm2, along cyclability greater than 3000 cycles. These high-performance results suggest laser-scribed nanostructures as remarkable candidates environment-friendly, large-scale low-cost applications.
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ژورنال
عنوان ژورنال: Carbon
سال: 2021
ISSN: ['0008-6223', '1873-3891']
DOI: https://doi.org/10.1016/j.carbon.2021.01.129